Catalytic and antimicrobial potential of green synthesized Au and Au@Ag core-shell nanoparticles

It has been a never-ending quest to design a safe, cost-effective, and environmentally acceptable technology for eliminating contaminants from water and countering antibiotic resistance. Herein, a waste leaf extract from the abundant and renewable plant, Brassica oleracea var. gongylodes, is introduced as a cost-effective and sustainable means to generate gold (Au) and Au@Ag core-shell nanoparticles (NPs). In comparison to the bare Au NPs, bimetallic NPs demonstrated improved catalytic and antibacterial capabilities. The reduction process conforms to the pseudo-first-order kinetic, and apparent rate constant (k_app) was calculated to be 0.46 min⁻¹, according to the kinetic analysis. With both microbial pathogens, E. coli (Gram-negative) and B. subtilis (Gram-positive), an increment of Au and Au@Ag NPs lead to a considerable improvement in the zone of clearance. The present outcome is a step forward in the establishment of a viable and cost-effective catalytic and antibacterial platform based on bimetallic NPs that could be generated in an inexpensive and eco-friendly manner.