TY - JOUR
T1 - Density modeling of chlorinated brines in two and three-component systems
AU - Soto-Bubert, Andrés
AU - Miranda, Joaquin
AU - Acevedo, Roberto
AU - Bhardwaj, Rashmi
AU - Rajendran, Satheeshkumar
N1 - Publisher Copyright:
© 2024 The Authors
PY - 2024/9
Y1 - 2024/9
N2 - The paper presents a semi-empirical approach to determining densities of chlorinated brines in the 0–4 molal concentration range and 293.15–323.15 K temperature range. This model incorporates continuous density functions for chlorinated salts and temperature, offering enhanced accuracy and reduced errors in density estimations for complex brine systems, including ternary systems. The model provides precise density estimations for applications like seawater and salt flats by considering ion activities and specific concentration ranges. Comparative analysis shows the model's superior performance with error adjustments consistently below 0.2 %. The continuous variable temperature model proves more effective than discrete approaches, contributing to more accurate density predictions.
AB - The paper presents a semi-empirical approach to determining densities of chlorinated brines in the 0–4 molal concentration range and 293.15–323.15 K temperature range. This model incorporates continuous density functions for chlorinated salts and temperature, offering enhanced accuracy and reduced errors in density estimations for complex brine systems, including ternary systems. The model provides precise density estimations for applications like seawater and salt flats by considering ion activities and specific concentration ranges. Comparative analysis shows the model's superior performance with error adjustments consistently below 0.2 %. The continuous variable temperature model proves more effective than discrete approaches, contributing to more accurate density predictions.
KW - Chlorinated brines
KW - Concentration ranges
KW - Density of ternary solutions
KW - Model to real-world systems
KW - Temperature
UR - http://www.scopus.com/inward/record.url?scp=85200315833&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/276634d6-06bd-3320-9754-7772db9b829b/
U2 - 10.1016/j.ctta.2024.100137
DO - 10.1016/j.ctta.2024.100137
M3 - Article
AN - SCOPUS:85200315833
SN - 2667-3126
VL - 15
JO - Chemical Thermodynamics and Thermal Analysis
JF - Chemical Thermodynamics and Thermal Analysis
M1 - 100137
ER -